hydrosilylation相关论文
Organosilicon materials are used as additives in a wide variety of products and generally provide or enhance specific at......
Development of Bifunctional Catalyst for Asymmetric Reduction of β-Amino Nitroolefins by Trichlorosi
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Rare-earth amides and alkyls display unique chemical properties because of the highly Lewis acidic metal ions,and thus a......
Copper-catalyzed highly efficient hydrosilylation reaction of enynoates was developed.Under simple reaction conditions,v......
Palladium-catalyzed hydrosilylation of ynones to access silicon-stereogenic silylenones by stereospe
Hydrosilylation is one of the most important reactions in synthetic chemistry and ranks as a fundamental method to acces......
Non-Noble Metals for Noble Tasks-Efficient Homogeneous Hydrogenations and Hydrosilylations with Midd
Replacing noble metals in homogeneous catalysis is a great and timely challenge for academic and industrial research.How......
Main observation and conclusion rnCatalytic diastereodivergent hydrosilylative enyne cyclization with high generality an......
建立了苯乙烯与甲基二乙氧基硅烷硅氢化反应体系中各组分含量测定的气相色谱检测方法。在GC-14B气相色谱仪(HP-5毛细管柱、FID检测......
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为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
Asymmetric Hydrosilylation of Aromatic Ketones Catalyzed by an Economical and Effective Copper-Dipho
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
Diverse Fates of β-Silyl Radical under Manganese Catalysis: Hydrosilylation and Dehydrogenative Sily
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
Metal-organic frameworks-derived nitrogen-doped carbon supported nanostructured PtNi catalyst for en
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
THE HYDROSILATION REACTION OF LADDERLIKE POLYALLYLSILSESQUIOXANE (ALLYL-T) AND POLYHYDROSILSESQUIOXA
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
SYNTHESIS AND CHARACTERIZATION OF A NOVEL REACTIVE LADDER-LIKE POLYSILSESQUIOXANE WITH LATERAL BROMO
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
为探究吕家坨井田地质构造格局,根据钻孔勘探资料,采用分形理论和趋势面分析方法,研究了井田7......
Hydrogen-containing polysilanes and chromophore-containing polysilanes are prepared by traditional Wurtz coupling and su......
A novel reactive polyorganosiloxane containing nitro groups was first prepared by acid-catalyzed equilibration polymeriz......
THE HYDROSILATION REACTION OF LADDERLIKE POLYALLYLSILSESQUIOXANE (ALLYL-T) AND POLYHYDROSILSESQUIOXA
The one plus one (1 + 1) mode of hydrosilation reaction of ladderlike cis-isotatic polyallylsilsesquioxane (AllyI-T)and ......
SYNTHESIS AND CHARACTERIZATION OF A NOVEL REACTIVE LADDER-LIKE POLYSILSESQUIOXANE WITH LATERAL BROMO
A novel soluble, reactive ladder-like polysilsesquioxane (L) with lateral bromophenyl groups was synthesized successfull......
Pt Complexes with High Molecular Weight Polyvinylmethyldimethylsiloxane Ligands Supported on Diatomi
Pt complexes with high molecular weight polyvinylmethyldimethylsiloxane (HMPVMS)ligands supported on diatomite as a cata......
In this work, the preparation of α, ω-dichloride-terminated multi-vinyl branched siloxane 1 (yield: 57.1%) used for se......
Synthesis and characterization of α-{3-[2-hydroxy-3-(N-methyl-N-hydroxy-ethylamino)propoxy]propyl}-ω
α-{3-[2-hydroxy-3-(N-methyl-N-hydroxyethylamino)propoxy]propyl}-ω-butylpolydimethylsiloxanes Ⅲ with various moleculax......
以八甲基环四硅氧烷(D4)、四甲基环四硅氧烷(D4^H)和六甲基硅氧烷(MM)为原料实施开环聚合反应,制备出不同含氢量的聚二甲基硅氧烷;......
Synthesis of Calix[4]dithiacrown Platinum Complexes and Their Catalytic Behavior in the Hydrosilylat
5,11,17,23-Tetrakis-1 ， 1-dimethylethyl-25,27-dihydroxy-26,28-1 ， 7 ， 13-trioxa-4 ， 10-dithiatridecylcene-calix [ 4 ] arene ......
以SiO2为载体，将壳聚糖（CS）负载到SiO2上，利用CS对Pt的螯合作用，制备了SiO2负载CS络合Pt配合物（SiO2-CS-Pt）；采用X射线衍射、傅里叶变换红......
以笼型八聚（二甲基硅氧基）倍半硅氧烷（POSS1）为原料，在Karstedt催化剂的催化作用下，通过硅氢加成与乙烯基二茂铁反应，合成了八取代二茂铁......
<正> 高分子负载膦铂配合物是一类很好的烯烃硅氢加成催化剂,但迄今未见有关螯合型双膦铂配位负载催化剂的报道。1983年,Micholska......
γ-巯丙基三甲氧基硅烷与β-氯乙基二甲胺盐酸盐在甲醇钠存在下缩合,得到4-硫杂-6-二甲胺基己基三甲氧基硅烷。后者以气相法二氧化......
研究了固载液相铂催化剂的制备及其在3-氯丙烯与甲基二氯硅烷硅氢加成反应中的催化性能；该催化剂对连续式气-固相硅氢加成反应具有......
硅氢加成反应是有机硅化学中制备含Si-C化合物的一类重要反应.综述了硅氢加成反应中负载型金属配合物催化剂的种类、催化性能及催......
在铂络合物催化剂的作用下，以高碳数烯烃化合物和含氢硅油为原料，利用硅氢加成反应合成有机硅蜡。研究了原料配比、催化剂用量、反应......
ＳｔｕｄｉｅｓＯｎＡＳｅｌｅｎａ┐ａｚａ┐ｃｒｏｗｎＥｔｈｅｒ：ＳｙｎｔｈｅｓｉｓａｎｄＣａｔａｌｙｔｉｃＢｅｈａｖｉｏｒＩｎＨｙｄｒｏｓｉｌｙｌａｔｉｏｎＸｕＷｅｉ，ＬｉｕＸｉｕｆａｎｇ，ＬｕＸｕｅｒａｎ，ＸｕＨａｎｓｈｅｎｇＤｅｐａｒｔｍｅｎｔ.........
Ｓｔｕｄｙｏｎｔｈｅｃａｔａｌｙｔｉｃｂｅｈａｖｉｏｒｏｆｆｕｌｅｒｅｎｅｄｅｒｉｖａｔｉｖｅｓｉｓｏｎｅｏｆｔｈｅｉｍｐｏｒｔａｎｔｆｉｅｌｄｓｉｎｆｕｌｅｒｅｎｅｓｃｉｅｎｃｅ．Ｉｔｗａｓｆｏｕｎｄｔｈａｔｍａｎｙｆｕｌｅｒｅｎｅｍｅｔａｌｃｏｍ.........
Synthesis and characterization of luminescent organic-inorganic hybrid nanocomposite from polyhedral
A novel polyhedral oligomeric silsesquioxane (POSS)-based organic-inorganic hybrid nanocomposite (EF-POSS) was prepared ......
通过硅氢化加成及还原反应，将四烯丙基硅烷（Gn）官能化，制备端基为4个si—H键的碳硅烷枝状分子。考察不同的催化剂、溶剂、投料方式及温......
将壳聚糖（CS）负载到碳纳米管（CNT）上得到CNT—CS，再与Pt配位，制得CNT负载cs络合铂配合物（CNT—CS—Pt）。将后者用作烯丙基缩水甘油醚和三乙......
本课题主要研究辛基七甲基三硅氧烷的合成。在铂金催化剂下,使用辛烯与七甲基三硅氧烷进行硅氢化加成反应,一步生成辛基七甲基三硅......
以传统Karstedt催化剂为基础,通过加入N、P化合物和含不饱和基的大分子化合物进行配位体的置换反应,制得3种具有抑制作用的铂配合......
环氧改性聚硅氧烷不仅具有普通聚硅氧烷的各种优异性能,还具有环氧基团的高强度粘接性、低收缩率、加工性能好等优点。另外,环氧改......
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polyhydrosiloxane 和与酉旨组一起终止的不饱和的烯丙基氯化聚醚的 hydrosilylation 作为溶剂作为催化剂和乙酸乙酯与氢氯铂酸的......
Effect of Aminoaromatic Acids as Additives on the Activity and Selectivity of the Platinum-catalyzed
一系列芳香的酸与 triethoxysilane 为苯乙烯的催化铂的 hydrosilylation 作为添加剂被测试了。两赞成 β 的苯乙烯和选择的优......
以苯基三甲氧基硅烷和乙烯基三甲氧基硅烷为原料,在金属离子诱导作用下水解缩聚制得具有环形结构的三苯基三硅氢环三硅氧烷和六乙......
以苯基含氢硅油和烯丙基甲基聚醚为原料,异丙醇为溶剂,氯铂酸为催化剂,通过硅氢加成反应合成聚醚改性苯基含氢硅油非离子表面活性......
